Giúp tớ với được không? Cho 20g Cu vào cốc đựng 0,5l dung dịch AgNO3 0,3M. Khuấy đều sau một thời gian lọc thì thu được 29,12g chất rắn và dung dịch A a, tính nồng độ mol các chất trong dung dịch A ( biết V không đổi)

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Đặt $n_{Cu}=x(mol)$

$n_{AgNO_3}=0,5.0,3=0,15(mol)$

$PTHH:Cu+2AgNO_3\to Cu(NO_3)_2+2Ag\downarrow$

Theo PT: $n_{Ag}=2n_{Cu}=2x(mol)$

Ta có $m_{KL tăng}=m_{Ag}-m_{Cu}=108.2x-64x=29,12-20$

$\Rightarrow 152x=9,12$

$\Rightarrow x=0,06(mol)$

Lập tỉ lệ so sánh: $\dfrac{n_{Cu}}{1}<\dfrac{n_{AgNO_3}}{2}\Rightarrow AgNO_3$ dư

$\Rightarrow n_{AgNO_3(dư)}=0,15-0,06.2=0,03(mol)$

Theo PT: $n_{Cu(NO_3)_2}=n_{Cu}=0,06(mol)$

$\Rightarrow C_{M_{AgNO_3(dư)}}=\dfrac{0,03}{0,5}=0,06M$

$C_{M_{Cu(NO_3)_2}}=\dfrac{0,06}{0,5}=0,12M$

n AgNO3 = 0,5×0,3 = 0,15 mol m Tăng = (108×2-64)a = 9,12 -) a = 0,06 mol -) n AgNO3 dư = 0,15 - 0,06 = 0,09 mol -) [AgNO3] = 0,09/0,5 = 0,18M [Cu(NO3)2] = 0,06/0,5 = 0,12M
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