Trả lời bởi giáo viên
\(NaOH \to N{a^ + } + O{H^ - }\)
10-3 \( \to\) 10-3
\(N{H_3} + {H_2}O \rightleftarrows NH_4^ + + O{H^ - }\)
Ban đầu: 0,01 10-3
Phân li: x x 10-3 + x
Cân bằng 0,01 – x x 10-3 + x
Vì \({K_{b(N{H_3})}} = \dfrac{{{\text{[}}O{H^ - }{\text{]}}.{\text{[}}NH_4^ + {\text{]}}}}{{{\text{[}}N{H_3}{\text{]}}}} \to 1,{8.10^{ - 5}} = \dfrac{{({{10}^{ - 3}} + x)x}}{{0,01 - x}} \to x = 1,{536.10^{ - 4}}\)
\( \to {\text{[}}O{H^ - }{\text{]}} = 1,{536.10^{ - 4}} + {10^{ - 3}} = 11,{536.10^{ - 4}}\,\,M\)
\( \to pH = 14 + \log (11,{536.10^{ - 4}}) = 11,062\)
Hướng dẫn giải:
\(NaOH \to N{a^ + } + O{H^ - }\)
10-3 \( \to\) 10-3
\(N{H_3} + {H_2}O \rightleftarrows NH_4^ + + O{H^ - }\)
Ban đầu: 0,01 10-3
Phân li: x x 10-3 + x
Cân bằng 0,01 – x x 10-3 + x
Vì \({K_{b(N{H_3})}} = \dfrac{{{\text{[}}O{H^ - }{\text{]}}.{\text{[}}NH_4^ + {\text{]}}}}{{{\text{[}}N{H_3}{\text{]}}}} \)
\( \to {\text{[}}O{H^ - }{\text{]}} \)
\( \to pH \)